先进碳材料科学与工程(英文版) 作者:(日)稻垣道夫 着 出版时间:2013年 内容简介 《先进碳材料科学与工程》由稻垣道夫着。由于富勒烯和石墨烯分别获得了1996年诺贝尔化学奖和2010年诺贝尔物理奖,加上1991年发现的纳米炭管,引发了世界范围内的纳米科技革命。碳材料无论在科技界还是工业界都是热点,各国投入了大量的财力物力进行研究开发。《先进碳材料科学与工程》结合作者(稻垣道夫)们在碳材料科学与工程的最新研究成果,重点介绍了碳材料的合成、表征和应用方面的新近进展,深入浅出、图文并茂,适合于广大读者自学或者用作教材。 目录 Preface Acknowledgment CHAPTER 1 Introduction 1.1 Classification of carbon materials 1.2 Nanotexture of carbon materials 1.3 Microtexture of carbon materials 1.4 Specification of carbon materials 1.5 Construction of the present book References CHAPTER 2 Carbon Nanotubes: Synthesis and Formation 2.1 Synthesis of carbon nanotubes 2.2 Formation of carbon nanotubes 2.2.1 Formation into yarns 2.2.2 Formation into sheets 2.2.3 Formation into sponges 2.3 Applications of carbon nanotubes 2.4 Concluding remarks References CHAPTER 3 Graphene: Synthesis and Preparation 3.1 Preparation through the cleavage of graphite 3.2 Preparation through the exfoliation of graphite 3.2.1 Preparation using graphite oxides 3.2.2 Preparation using graphite intercalation compounds 3.3 Synthesis through chemical vapor deposition 3.4 Synthesis through the organic route 3.5 Preparation through other processes 3.6 Concluding remarks References CHAPTER4 Carbonization Under Pressure 4.1 Carbonization under built—up pressure 4.1.1 Setup for carbonization under pressure 4.1.2 Optical texture and carbonization yield 4.1.3 Particle morphology 4.2 Carbonization under hydrothermal conditions 4.3 Carbonization under supercritical conditions 4.4 Concluding remarks 4.4.1 Temperature and pressure conditions for carbonization 4.4.2 Composition of precursors for the formation of carbon spheres References CHAPTER 5 Stress Graphitization 5.1 Graphitization under pressure 5.1.1 Structural change in carbons 5.1.2 Mechanism 5.2 Graphitization in coexistence with minerals under pressure 5.2.1 Coexistence with calcium compounds 5.2.2 Coexistence with other minerals 5.2.3 Mechanism for acceleration of graphitization 5.3 Stress graphitization in carbon/carbon composites 5.3.1 Acceleration of graphitization 5.3.2 Mechanism 5.4 Concluding remarks 5.4.1 Graphitization under pressure 5.4.2 Occurrence of graphite in nature 5.4.3 Stress graphitization in carbon/carbon composites References CHAPTER 6 Glass—like Carbon: Its Activation and Graphitization 6.1 Activation of glass—like carbon 6.1.1 Glass—like carbon spheres 6.1.2 Activation in a flow of dry air 6.1.3 Activation in a flow of wet air 6.1.4 Activation process 6.1.5 Direct observation of micropores 6.1.6 Two—step activation 6.2 Graphitization of glass—like carbons 6.2.1 Graphitization through melting 6.2.2 Graphitization under high pressure 6.2.3 Graphitization in C/C composites 6.3 Concluding remarks References CHAPTER 7 Template Carbonization: Morphology and Pore Control 7.1 Template carbonization for morphological control 7.1.1 Inorganic layered compounds 7.1.2 Anodic aluminum oxide films 7.1.3 Organic foams 7.2 Template carbonization for pore—structure control 7.2.1 Zeolites 7.2.2 Mesoporous silicas 7.2.3 MgO 7.2.4 Block copolymer surfactants (soft templates) 7.2.5 Metal—organic frameworks 7.2.6 Other templates 7.3 Concluding remarks References CHAPTER 8 Carbon Nanofibers Via Electrospinning 8.1 Carbon nanofibers synthesized via electrospinning 8.1.1 Polyacrylonitrile 8.1.2 Pitch 8.1.3 Polyimides 8.1.4 Poly(vinylidene fluoride) 8.1.5 Phenolic resins 8.2 Applications 8.2.1 Electrode materials for electrochemical capacitors 8.2.2 Anode materials for lithium—ion rechargeable batteries 8.2.3 Catalyst support 8.2.4 Composite with carbon nanotubes 8.3 Concluding remarks 8.3.1 Carbon precursors 8.3.2 Pore—structure control 8.3.3 Improvement of electrical conductivity 8.3.4 Loading of metallic species References CHAPTER 9 Carbon Foams 9.1 Preparation of carbon foams 9.1.1 Exfoliation and compaction of graphite 9.1.2 Blowing of carbon precursors 9.1.3 Template carbonization 9.2 Applications of carbon foams 9.2.1 Thermal energy storage 9.2.2 Electrodes 9.2.3 Adsorption 9.2.4 Other applications 9.3 Concluding remarks References CHAPTER 10 Nanoporous Carbon Membranes and Webs 10.1 Synthesis 10.1.1 Pyrolysis and carbonization of organic precursors 10.1.2 Templating i0.1.3 Chemical and physical vapor deposition 10.1.4 Formation of carbon nanotubes and nanofibers 10.2 Applications 10.2.1 Adsorbents 10.2.2 Separation membranes 10.2.3 Chemical sensors and biosensors 10.2.4 Electrodes i 10.2.5 Other applications 10.3 Concluding remarks References CHAPTER 11 Carbon Materials for Electrochemical Capacitors 11.1 Symmetrical supercapacitors 11.1.1 Activated carbons 11.1.2 Templated carbons 11.1.3 Other carbons 11.1.4 Carbons containing foreign atoms 11.1.5 Carbon nanotubes and nanofibers 11.2 Asymmetrical supercapacitors 11.3 Asymmetrical capacitors 11.4 Carbon—coating of electrode materials 11.5 Concluding remarks References CHAPTER 12 Carbon Materials in Lithium—ion Rechargeable Batteries 12.1 Anode materials 12.1.1 Materials 12.1.2 Carbon coating of graphite 12.1.3 Carbon coating of Li4T15O12 12.2 Cathode materials 12.2.1 Materials 12.2.2 Carbon coating of LiFePO4 12.3 Concluding remarks References CHAPTER 13 Carbon Materials in Photocatalysis 13.1 TiO2—1oaded activated carbons 13.2 Mixture of activated carbon and TiO2 13.3 Carbon—doped TiO2 13.4 Carbon—coated TiO2 13.5 Synthesis of novel photocatalysts via carbon coating 13.5.1 Carbon—coated Ti O2n—1 13.5.2 Carbon—coated W18049 13.5.3 TiO2 co—modified by carbon and iron 13.6 Concluding remarks References CHAPTER 14 Carbon Materials for Spilled—oil Recovery 14.1 Sorption capacity for heavy oils 14.1.1 Exfoliated graphite 14.1.2 Carbonized fir fibers 14.1.3 Carbon fibers 14.1.4 Carbon nanotube sponge 14.1.5 Other carbon materials 14.2 Selectivity of sorption 14.3 Sorption kinetics 14.4 Cycle performance of carbon sorbents and heavy oils 14.5 Preliminary experiments for practical recovery of spilled heavy oils 14.5.1 Exfoliated graphite packed into a plastic bag 14.5.2 Formed exfoliated graphite 14.5.3 Heavy oil sorption from contaminated sand 14.5.4 Sorption of heavy—oil mousse 14.5.5 TiO2—1oaded exfoliated graphite 14.6 Concluding remarks 14.6.1 Comparison among carbon materials 14.6.2 Mechanism of heavy oil sorption 14.6.3 Comparison with other materials References CHAPTER 15 Carbon Materials for Adsorption of Molecules and Ions 15.1 Adsorption and storage of hydrogen 15.2 Adsorption and storage of methane and methane hydrate 15.3 Adsorption and storage of CO2 15.4 Adsorption of organic molecules 15.4.1 Organic gases (including VOCs) 15.4.2 Organic molecules in water 15.5 Adsorption and removal of heavy—metal ions in water 15.6 Capacitive deionization 15.7 Concluding remarks References CHAPTER 16 Highly Oriented Graphite with High Thermal Conductivity 16.1 Preparation 16.2 Characterization 16.3 Carbon materials with high thermal conductivity 16.3.1 Pyrolytic graphite 16.3.2 Polyimide—derived graphite 16.3.3 Natural graphite and its composites 16.3.4 Carbon fibers 16.3.5 Carbon nanotubes and graphene 16.3.6 Diamond and diarnond—like carbons 16.4 Concluding remarks References CHAPTER 17 Isotropic High—density Graphite and Nuclear Applications 17.1 Production 17.2 Properties 17.3 Nuclear applications 17.3.1 Fission reactors 17.3.2 Fusion reactors 17.4 Concluding remarks References INDEX 上一篇: 现代材料测试技术 下一篇: 小冲孔微试样材料性能测试技术及应用